Improved acetone sensing properties of flat sensors based on Co-SnO2 composite nanofibers

Co-SnO2 composite nanofibers were synthesized by an electrospinning method and characterized by X-ray diffraction, field emission scanning electron microscopy, and transmission electron microscopy. Gas sensors were fabricated by spinning these nanofibers onto flat ceramic substrates, which had signal electrodes and heaters on their top and bottom surfaces, respectively. Compared with sensors loaded with pure SnO2 nanofibers, the Co-SnO2 nanofiber sensors exhibited improved acetone sensing properties with high selectivity and rapid response and recovery times. The response was 33 when the sensors were exposed to 100 μL/L acetone at 330°C, and the corresponding response with 100 μL/L of ethanol was only 6. The response and recovery times to acetone were about 5 and 8 s, respectively. These results indicate Co-SnO2 composite nanofibers are good candidates for fabrication of high performance acetone sensors for practical application.     

Evolution of the East Asian monsoon and its response to uplift of the Tibetan Plateau since 1.8 Ma recorded by major elements in sediments of the South China Sea

Evolution of the East Asian monsoon and its response to uplift of the Tibetan Plateau has been investigated in the study of global change. Core sediment samples drilled in the South China Sea during ODP Leg184 are the best materials for studying long-term variability of the East Asian monsoon. R-mode factor analysis of major elements in the fine grain-sized carbonate-free sediments (<4 μm) of the upper 185 mcd splice of ODP Site 1146 drilled during Leg184 in the South China Sea shows that Ti, TFe2O3, MgO, K2O, P, CaO, and Al2O3 are representative of a terrestrial factor. The variation in the terrestrial factor score is subject to chemical erosion in the source region and thus indicates the evolution of the East Asian summer monsoon. The terrestrial factor score has three stepwise decreases at ~1.3 Ma, ~0.9 Ma, and ~0.6 Ma, indicating the phased weakening of the East Asian summer monsoon is related to wholly stepwise, quick uplifts of the Tibetan Plateau since 1.8 Ma. The periodic fluctuation of the terrestrial factor score since ~0.6 Ma indicates that the glacial-interglacial cycles have been the main force driving the evolution of the East Asian monsoon. As in the case of Chinese loess, the long-term evolution of the East Asian monsoon recorded in sediments of the South China Sea reflects a coupled effect of the glacial-interglacial cycle and uplift of the Tibetan Plateau.     

壳聚糖/ZnO复合材料制备及表征

通过在壳聚糖(CS)溶液中掺入乙酸锌制备了Zn2+/CS复合膜,采用化学溶液沉积法,在Zn2+/CS复合膜上生长氧化锌(ZnO),并通过改变生长液的组成成分寻找其最简单、优化的试验方案.通过UV-Vis、XRD和SEM表征,对样品进行分析研究.结果表明,在Zn(NO)3.6H2 O和NaOH组成的化学溶液环境中,Zn2+/CS复合膜中的ZnO最易生长,在Zn2+/CS复合膜的表面首先形成了一层ZnO粒子膜,然后ZnO粒子长大成六角纤锌结构、没有明显的择优取向的ZnO棒.光学性能测试显示ZnO/壳聚糖复合材料具有良好的光致发光性能.电阻率的测定表明ZnO/壳聚糖复合材料是一种防静电材料.     

絮凝过滤在石化废水深度处理中的应用研究

通过小试实验,比较分析无机、有机及复合絮凝剂对某石化企业污水处理厂出水的絮凝效果,通过处理效果和成本分析,筛选得到了聚合氯化铝-聚二甲基二烯丙基氯化铵复合絮凝剂(PAC-PDMDAAC).该絮凝剂在投加量为50 mg.L-1时,浊度最大去除率为72.4%;在实验投加量范围内,CODC r去除率均在40%以上;投加量为40 mg.L-1时,最大去除率达59.3%.在小试的基础上,将该絮凝剂应用于中试实验,分析监测不同构筑物对CODC r的去除效果等参数,确定了合理的投药量、排泥量、反冲洗时间、沉淀时间、处理水量等指标.     

亚微米Fe包Co空心微球的制备

研究了一种制备Fe包Co空心微球的新方法.以纳米铁粒子为模板,水合肼为还原剂,通过化学镀制备出具有核-壳结构的Co包Fe纳米粒子,用HCl溶去Fe核制备出空心Co微球,以空心Co微球为模板,NaBH4为还原剂,通过化学镀Fe制备了亚微米Fe包Co的空心微球.研究发现,在化学镀Fe过程中,Fe包Co空心微球之间极易形成硬黏结,通过降低反应物浓度和反应温度,增大反应液pH值抑制镀液中Fe粒子的独立形核,则可明显防止Fe包Co空心微球之间硬黏结的发生.     

铝合金表面构建超疏水性的化学改性机理

系统研究了刻蚀一化学改性两步法中的蒸镀改性工艺对铝合金表面形貌和润湿性的影响,提出了刻蚀与化学改性同时进行的一步浸泡法制备超疏水铝合金.结果表明,两步法蒸镀改性工艺中,硬脂酸端部的极性亲水羧基与铝合金表面羟基以共价键结合,从而在铝合金表面形成一层硬脂酸膜,使铝合金实现低表面能化,水滴在其表面处于Cassie状态,接触角...     

惠民南部地区油水物化性质与油气运移方向和模式

油水物化性质变化可以从古水文演化角度反应油气运移方向.本文以惠民凹陷南部地区沙河街组三段为例,利用原油密度、黏度、地层水矿化度、水型及离子组合参数变化特征,研究油气运移规律.平面上,研究区原油密度、黏度整体具有西北高、东南低的分布规律,局部具有一低四高的分布特征,反映出原油密度、黏度随运移距离的增加而增大;地层水矿化度具有以夏口断裂为中心,向南北两侧逐渐变小的分布特征,矿化度高值区的分布与夏口断层油气运移聚集有关;地层水水型和离子组合参数变化特征表明沿夏口断裂带具有两个油气聚集区,分别为双丰、江家店-瓦屋鼻状构造.通过对油气运聚关系的分析,以油气源、输导因素为基础,沿油气主要运移方向,建立了研究区近源侧向砂体输导、近源混向反Z型输导、远源混向阶梯状输导、远源混向多级反Z型输导4种油气运移模式.     

藜中黄酮类的化学成分

采用正、 反相硅胶和葡聚糖凝胶柱色谱技术对藜（Chenopodium album L.）的黄酮类化学成分进行分离和纯化, 得到4个黄酮类化合物, 分别
为槲皮素3-O-芸香糖苷(1)、 芹菜素6,8-二-C-β-D-葡萄糖苷(2)、 槲皮素3-O-［α-L-鼠李糖（1→4）-α-L-鼠李糖（1→6）-β-D-葡萄糖］(3)、 异鼠李素3-O-［α-L-鼠李糖（1→4）-α-L-鼠李糖（1→6）-β-D-葡萄糖］(4). 其中化合物2、3、4为首次从该属植物中分离得到.     

塑料食品包装材料化学物迁移的数值方法

塑料包装材料内含化学物向食品迁移会造成食品污染并危害消费者健康.近年来,对迁移理论的预测逐渐成为热点.现将谱方法应用于塑料食品包装化学物迁移的数学模型,给出了模型问题的Chebyshev配点法,并进行稳定性和收敛性分析.     

基于AUSMDV格式的高超声速钝体绕流的数值模拟

围绕高超声速高温流场的高温效应问题,采用有限体积法,以及熵修正的AUSMDV格式,利用时间分裂法求解了完全气体和化学非平衡流场。求解了SOD2激波管问题,并与精确解进行了对比,分析和验证了AUSMDV格式捕获间断的能力。化学非平衡流求解中采用Park化学动力模型,化学反应源项采用准定常法(The New Quasi-Steady-State-Approach)处理,克服了化学反应源项引起的刚性问题,结果与CEA程序的计算结果进行了比较,研究了高超声速圆柱绕流流场,分析了化学反应对流场的影响。结果证明了计算方法与程序的有效性和实用性。